Assuming ideal conditions, Boyle's law says that
P₁ V₁ = P₂ V₂
where P₁ and V₁ are the initial pressure and temperature, respectively, and P₂ and V₂ are the final pressure and temperature.
So you have
(455 mm Hg) (56.5 m³) = (632 mm Hg) V₂
==> V₂ = (455 mm Hg) (56.5 m³) / (632 mm Hg) ≈ 40.7 m³
